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Chapter 0
chemistry • matric 10th

Chemical Industries

Comprehensive notes, solved MCQs, and Short Questions for Class 10 Chemistry Chapter 16 Chemical Industries. Covers Metallurgy (Copper Extraction), Solvay Process (Sodium Carbonate), Urea Manufacturing, Petroleum Industry.

Basic Metallurgical Operations

Mineral vs Ore: Minerals are natural materials containing metals. Ores are minerals from which metals can be extracted commercially/profitably. Gangue: Earthly impurities in ores.

Concentration Methods: Refers to removal of gangue.

  • Gravity Separation: Based on density difference. Heavy ore settles, lighter gangue flows away.
  • Froth Floatation: For Sulphide ores. Ore wetted by oil (floats), gangue wetted by water (sinks).
  • Electromagnetic Separation: For magnetic ores (or impurities).

Extraction of Copper

Roasting: Heating ore (Copper Pyrite CuFeS2) in excess air. 2CuFeS2 + O2 -> Cu2S + 2FeS + SO2.

Smelting: Roasted ore + Sand + Coke heated in Blast Furnace. Ferrous Sulphide oxidizes to FeO and reacts with Sand (SiO2) to form Slag (FeSiO3). Product is Matte (Cu2S + FeS).

Bessemerization: Molten matte heated in Bessemer converter. FeS removed as slag. Cu2S oxidizes to Cu2O which reacts with remaining Cu2S to form Metallic Copper. Product is Blister Copper (98% pure, blistered surface due to escaping gases).

Refining: Electrolyte: CuSO4. Anode: Impure Copper. Cathode: Pure Copper. 99.9% pure copper deposits on cathode.

Solvay's Process (Manufacturing of Sodium Carbonate)

Principle: Low solubility of Sodium Bicarbonate at 15°C.

Raw Materials: Sodium Chloride (Brine), Limestone (CaCO3), Ammonia (NH3).

Steps:

  1. Preparation of Ammonical Brine.
  2. Carbonation: Ammonical brine + CO2 -> NaHCO3 (ppt) + NH4Cl.
  3. Filtration: NaHCO3 separated.
  4. Calcination: Heating NaHCO3 to get Sodium Carbonate (Na2CO3/Soda Ash) and CO2.
  5. Ammonia Recovery: NH4Cl + Ca(OH)2 -> NH3 + CaCl2 + H2O.

Advantages: Cheap raw materials, polliution free, NH3/CO2 are reused.

Manufacture of Urea

Urea (NH2CONH2): Nitrogenous fertilizer (46.6% Nitrogen). White crystalline, highly soluble.

Raw Materials: Ammonia (NH3) from Haber's Process, Carbon Dioxide (CO2).

Process:

  1. Formation of Ammonium Carbamate: Liquid NH3 + CO2 -> NH2COONH4.
  2. Urea Formation: Evaporation of Ammonium Carbamate to form Urea. NH2COONH4 -> NH2CONH2 + H2O.
  3. Granulation: Liquid urea evaporated to form granules.

Fertilizers:
Natural: Manure, compost. Improves soil structure/texture.
Synthetic: Chemical fertilizers (N, P, K). Fast acting but can cause environmental issues (Eutrophication).

Petroleum Industry

Petroleum (Rock Oil): Complex mixture of hydrocarbons formed by decomposition of dead organic matter buried under Earth's crust (Organic Theory).

Refining: Fractional Distillation separation based on boiling points.

Important Fractions:

  • Petroleum Gas (bp < 25°C): Fuel (LPG), Carbon Black.
  • Petroleum Ether (30-80°C): Laboratory solvent, dry cleaning.
  • Gasoline/Petrol (80-170°C): Fuel for cars.
  • Kerosene Oil (170-250°C): Domestic fuel, Jet fuel.
  • Diesel Oil (250-350°C): Fuel for buses, trucks, railway engines.
  • Fuel Oil (350-400°C): Heating boilers, ships.
  • Residual Oil (>400°C): Lubricants, Paraffin wax, Asphalt (Road paving), Petroleum Coke.

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